If it weren't asking for a couple in anime I'd pick Kirito x Asuna. The light novel was great, especially chapter 16.5 >:3
The anime was terrible though. "Yeah, let's be cheap, save time for our animators and leave the camera on the same picture for five seconds straight, but make it zoomed in and scroll up and down so it looks like it's not cheap."
-.-
It had a good few episodes at the starting, but the quality dropped so much about ten episodes in...
Not the point though. Touma x Misaka sounds so delicious, but I'm gonna go with Taichi x Inaba.
This show is about your favourite pairing, not show, anyway.
Dunno why so many people vote for Kirito x Asuna when Kirito x Silica is clearly superior. :(
Why isn't Boondocks on this list???? Huey x Riley is the best romance in all of cartoons. Sword Art Online is full of stupid bitches and so is its audience.
If I could I would go with Saika and Hachiman from SNAFU since that show shouldn't end any other way (also because why not he loves the fuck outta traps). But since there is no write in ballot going with Araragi × Senjougahara (Bakemonogatari). (Also this poll pushed me into making an account(ya! for everyone))
Yuki and Yuno from Mirai Nikki. She's willing to die and kill herself in multiple dimensions just to be with her beloved Yuki. Their love tramples over the boundaries of space and time.
Only the concept of SAO anime was good. Nothing else was memorable unless you want to count modern animation. You might as well have read the manga or LN, and I doubt the hardcore fans of that pile of crap anime read the manga or LNs which were both piles of crap too.
A good concept that was not executed well. Get over it droolies and move on.